5-Hydroxymethylfurfural (HMF) Production from Real Biomasses

Integrated chemo-enzymatic production of 5-hydroxymethylfurfural from glucose.

Sweets for my sweet: The production and isolation of 5-hydroxymethylfurfural (HMF) in high yield and purity is demonstrated by using a combination of glucose-fructose isomerization with sweetzyme in wet tetraethylammonium bromide (TEAB) and clean fructose dehydration to HMF catalyzed by using HNO₃ under moderate conditions, which allow the reuse of any unreacted glucose and TEAB.

5-Hydroxymethylfurfural (5-HMF) Production from Hexoses: Limits of Heterogeneous Catalysis in Hydrothermal Conditions and Potential of Concentrated Aqueous Organic Acids as Reactive Solvent System

5-Hydroxymethylfurfural (5-HMF) is an important bio-sourced intermediate, 17 formed from carbohydrates such as glucose or fructose. The treatment at 150–250 °C of 18 glucose or fructose in pure water and batch conditions, with catalytic amounts of most of 19 the usual acid-basic solid catalysts, gave limited yields in 5-HMF, due mainly to the fast 20 formation of soluble oligomers. Niobic acid,...

Lycopene and Hydroxymethylfurfural (HMF) Evaluation in Tomato Products

Color of tomato products is due to the pigments content of fruit together with browning compounds originated during processing. To get a final product with a good is color is necessary to use fruits with an appropriated coloration and to avoid the degradation of pigments during post-harvest and processing. Final color should be bright and characteristic of each fruit. Lycopene, a liposoluble th...

The Margin of Exposure of 5-Hydroxymethylfurfural (HMF) in Alcoholic Beverages

OBJECTIVES 5-Hydroxymethylfurfural (HMF) regularly occurs in foods and in alcoholic beverages. However, the risk of HMF associated with alcohol consumption has not been systematically studied, so that this study will provide the first quantitative risk assessment of HMF for consumers of alcoholic beverages. METHODS Human dietary intake of HMF via alcoholic beverages in the European Union was ...

Efficient Conversion of Carbohydrates to 5-Hydroxymethylfurfural (HMF) Using ZrCl4 Catalyst in Nitromethane